Li-additives tsa rabara ke letoto la lihlahisoa tse ntle tsa lik'hemik'hale tse kenyellelitsoeng nakong ea ts'ebetso ea rabara ea tlhaho le rabara ea maiketsetso (e kopaneng e bitsoang "rabara e tala") lihlahisoa tsa rabara, tse sebelisetsoang ho fa lihlahisoa tsa rabara ts'ebetso, ho boloka bophelo ba ts'ebeletso ea lihlahisoa tsa rabara. , le ho ntlafatsa ts'ebetso ea ts'ebetso ea metsoako ea rabara.Li-additives tsa rabara li bapala karolo ea bohlokoa tokisong ea sebopeho sa lihlahisoa tsa rabara, nts'etsopele ea lihlahisoa tse ncha, ntlafatso ea theknoloji ea ts'ebetso ea rabara, ntlafatso ea ts'ebetso le boleng ba sehlahisoa sa rabara, 'me ke thepa e tala ea bohlokoa indastering ea rabara.
Rabara ea tlhaho lefatšeng e ile ea sibolloa ke Columbus ha a ne a sibolla Lefatše le Lecha ka 1493, empa e bile ka 1839 moo sebabole se neng se ka sebelisoa e le ntho e senyang rabara e kopanyang rabara, kahoo ea e fa molemo o sebetsang.Ho tloha ka nako eo ho ea pele, indasteri ea rabara ea lefatše e ile ea qala, ’me indasteri ea rabara le eona ea hōla.
Li-additives tsa rabara li ka aroloa ka meloko e meraro ho ea ka histori ea tsoelo-pele ea tsona, joalokaha ho hlalositsoe kenyelletsong e latelang.
Moloko oa pele oa li-additives tsa rabara 1839-1904
Lihlahisoa tsa tlatsetso ea rabara tsa nako ena li emeloa ke li-accelerator tsa inorganic vulcanization.Indasteri ea rabara e kene nakong ea li-accelerator tsa inorganic vulcanization, empa e boetse e na le mathata a kang ts'ebetso e tlase ea papatso le ts'ebetso e mpe ea vulcanization.
● 1839 Ho sibolla phello ea sebabole ho vulcanization ea rabara
● 1844 Ho sibolla li-accelerator tsa inorganic vulcanization
● 1846 Ho sibollotsoe hore sulfur monochloride e ka etsa hore rabara e "pholile vulcanize", e sebelisa amine carbonate joalo ka ntho e phophomang.
● 1904 E ile ea sibolla vulcanization active agent zinc oxide mme a fumana hore carbon black e na le phello e matlafatsang rabara.
Li-additives tsa rabara tsa moloko oa bobeli 1905-1980
Lihlahisoa tsa tlatsetso ea rabara tsa mehleng ena li ne li emeloa ke li-accelerator tsa organic vulcanization.Sesebelisoa sa pejana sa organic rubber vulcanization accelerator, aniline, se bile le phello e khothalletsang vulcanization, e ileng ea sibolloa ke setsebi sa k'hemistri sa Jeremane Oenslaber ka 1906 tekong ea United States.
● 1906 Ho qaptjoa ha organic vulcanization accelerators, thiourea type accelerators
● 1912 Ho qaptjoa ha dithiocarbamate sulfurization accelerator le ho qaptjoa ha p-aminoethylaniline
● 1914 Ho qaptjoa ha li-amine le β- Naphthylamine le p-phenylenediamine ho ka sebelisoa e le li-antioxidants.
● 1915 Ho qaptjoa ha organic peroxides, aromatics nitro compounds le zinc alkyl xanthate promoters
● 1920 Ho qaptjoa ha thiazole based vulcanization accelerators
● 1922 Ho qaptjoa ha mofuta oa guanidine vulcanization accelerator
● 1924 Ho qaptjoa ha antioxidant AH
● 1928 Ho qaptjoa ha antioxidant A
● 1929 Ho qaptjoa ha thiuram vulcanization accelerator
● 1931 Ho qaptjoa ha phenolic non polluting antioxidant
● 1932 Ho qaptjoa sulfosamide mofuta vulcanization accelerator DIBS、CBS、NOBS
● 1933 Ho qaptjoa ha antioxidant D
● 1937 Ho qaptjoa ha antioxidant 4010, 4010NA,4020
● Metsoako ea Diazo ea 1939 e ile ea qaptjoa ho senya rabara
● 1940 Ho qapa metsoako ea diazo ho vulcanize rabara
● 1943 Ho qaptjoa ha sekhomaretsi sa isocyanate
● 1960 Ho qaptjoa ha li-additives tsa rabara
● 1966 Ho qaptjoa ha sekhomaretsi sa Cohedur
● 1969 Ho qaptjoa CTP
● 1970 Ho qaptjoa li-accelerator tsa mofuta oa triazine
● 1980 Ho qaptjoa ha Manobond cobalt letsoai adhesion enhancer
Li-additives tsa rabara tsa moloko oa boraro 1980～
Ka mor'a lilemo tse fetang 100 tsa lipatlisiso, e bile feela ho fihlela lilemong tsa bo-1980 moo mefuta e mengata ea li-additives tsa rabara e ileng ea qala ho eketseha 'me tsamaiso e ntse e hōla le ho feta.Nakong ena, lihlahisoa tsa tlatsetso ea rabara li khetholloa ka likarolo tse tala le tse ngata.
● 1980-1981 Ntlafatso ea accelerator NS e qalile Chaena
● 1985 Qala MTT
● 1991 ~ Tsoela pele ho ntshetsa pele le ho qala ho sebelisa tikoloho e se nang nitrosamine kapa nitrosamine e sireletsehileng ea li-additives tse kang thiram, sulfonamide, li-accelerator tsa letsoai tsa zinki, li-vulcanizing agents, li-anti-coking agents, polasetiki, joalo-joalo, ZBPD、TBSI、CBBS、TBzTD、TIBTD、TIBTM、 ZDIBC, OTTOS, ZBEC, AS100, E/C, DBD le lihlahisoa tse ling li qapiloe ka ho latellana.
Nako ea poso: Jul-02-2023